A Facile MOF Based Iron-Molybdenum Bimetallic Electrode Material Preparation for Hydrogen Evolution


  • Yiduo Li
  • Ziqi Zhang
  • Hanbo Wang
  • Dongyu Pei
  • Sheng Wan
  • Yingying Li
  • Ming Zhao
  • Haiyan Lu




Hydrogen evolution, Bimetallic catalyst, Synergic catalytic effect.


Hydrogen energy has become the most potential energy source due to its high calorific value and environment-friendly combustion products. However, there are huge economic problems in hydrogen storage and transportation. Hydrogen can be prepared by catalysis in a way of reducing cost and speeding up speed which is the core idea of electrocatalytic water decomposition for hydrogen production. In this work, we developed an electrode material for Hydrogen evolution reaction (HER) bimetallic catalyst, and achieved that the hydrogen overpotential produced by acidic non-precious metal catalyst under acidic environment was only 275mV. More importantly, a good idea was provided for bimetallic co-catalysis of HER.


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Chen, Z., Duan, X., Wei, W., Wang, S. & Ni, B. J. Recent advances in transition metal-based electrocatalysts for alkaline hydrogen evolution. J. Mater. Chem. A 7, 14971–15005 (2019).

Lee, J. S. M., Parker, D. J., Cooper, A. I. & Hasell, T. High surface area sulfur-doped microporous carbons from inverse vulcanised polymers. J. Mater. Chem. A 5, 18603–18609 (2017).

Heinemann, N. D.-D. pd. et al. Enabling large-scale hydrogen storage in porous media-the scientific challenges. Energy Environ. Sci. 14, 853–864 (2021).

Karimi, F. et al. Characterization of LiBH4–MgH2 Reactive Hydride Composite System with Scattering and Imaging Methods Using Neutron and Synchrotron Radiation. Adv. Eng. Mater. 23, (2021).

Tang, H., Dou, K., Kaun, C. C., Kuang, Q. & Yang, S. MoSe2 nanosheets and their graphene hybrids: Synthesis, characterization and hydrogen evolution reaction studies. J. Mater. Chem. A 2, 360–364 (2014).

Bai, S., Jiang, J., Zhang, Q. & Xiong, Y. Steering charge kinetics in photocatalysis: Intersection of materials syntheses, characterization techniques and theoretical simulations. Chem. Soc. Rev. 44, 2893–2939 (2015).

Zhang, Z., Cong, L., Yu, Z., Qu, L. & Huang, W. Facial synthesis of Fe–Ni bimetallic N-doped carbon framework for efficient electrochemical hydrogen evolution reaction. Mater. Today Energy 16, 100387 (2020).

Yang, Q. et al. Single Carbon Vacancy Traps Atomic Platinum for Hydrogen Evolution Catalysis. J. Am. Chem. Soc. 144, 2171–2178 (2022).

Wu, Y. et al. An organometal halide perovskite supported Pt single-atom photocatalyst for H2 evolution†. Energy Environ. Sci. 15, 1271–1281 (2022).

Huang, G., Zhao, L., Yuan, S., Li, N. & Jing, S. Iron doped mesoporous cobalt phosphide with optimized electronic structure for enhanced hydrogen evolution. Int. J. Hydrogen Energy 47, 14767–14776 (2022).

Tsai, F. Te et al. Morphological and Electronic Optimization of Nanostructured FeCoNi-Based Electrocatalysts by Al Dopants for Neutral/Alkaline Water Splitting. ACS Appl. Energy Mater. (2022) doi:10.1021/acsaem.2c00238.

Yang, M. et al. Controlled high-density interface engineering of Fe3O4-FeS nanoarray for efficient hydrogen evolution. J. Energy Chem. 68, 96–103 (2022).

He, F. et al. Porous Nitrogen-Defected Carbon Nitride Derived from A Precursor Pretreatment Strategy for Efficient Photocatalytic Degradation and Hydrogen Evolution. Langmuir 38, 828–837 (2022).

Kim, T. et al. Highly Dispersed Pt Clusters on F-Doped Tin(IV) Oxide Aerogel Matrix: An Ultra-Robust Hybrid Catalyst for Enhanced Hydrogen Evolution. ACS Nano 16, 1625–1638 (2022).

Uyama, T., Okazaki, Y., Kawaguchi, S. & Yamada, I. Positive and Negative Synergistic Effects of Fe-Co Mixing on the Oxygen and Hydrogen Evolution Reaction Activities of the Quadruple Perovskite CaCu3Fe4- xCoxO12. ACS Appl. Energy Mater. 5, 214–226 (2022).




How to Cite

Li, Y., Zhang, Z., Wang, H., Pei, D., Wan, S., Li, Y., Zhao, M., & Lu, H. (2023). A Facile MOF Based Iron-Molybdenum Bimetallic Electrode Material Preparation for Hydrogen Evolution . Academic Journal of Science and Technology, 4(2), 137–140. https://doi.org/10.54097/ajst.v4i2.4190