Fe-S Co-doped Porous Carbon Catalyzed Oxidation and Degradation of Dye Wastewater

Ziyu Wang; Yi Wang; Bo Xing; Fuping Zhang; Liang Jiang; Chao Gao; Kunbiao Tang

doi:10.54097/b46py956

Authors

Ziyu Wang
Yi Wang
Bo Xing
Fuping Zhang
Liang Jiang
Chao Gao
Kunbiao Tang

DOI:

https://doi.org/10.54097/b46py956

Keywords:

Fenton Reaction; Fe-S Co-doping; Porous Carbon; Dye Wastewater.

Abstract

In this paper, Fe-S co-doping method of "one-step blending + high temperature carbonization activation" was used to prepare highly efficient Fenton-like catalyst. Rhodamine B (Rh B) was used as the research object, and H₂O₂ was used as the oxidant to catalyze the oxidation and degradation of Rh B. The important process conditions (reaction pH, reaction temperature, H₂O₂ addition, catalyst addition) were optimized, and the reaction mechanism and stability of the catalyst were investigated. The experimental results show that the initial concentration of Rh B is 50 mg/L, n(Fe): n(S) = 1.8:1, C source 9 g; Under the conditions of reaction pH = 2, reaction temperature 50℃ and catalyst dosage 0.02 g, the degradation rate of Rh B can reach 91.17%. XRD, BET and FT-IR results show that the prepared catalyst has good pore structure and abundant functional groups on its surface. The kinetic results show that the oxidation and degradation of Rh B by Fe-S co-doped Fenton-like catalyst conforms to the quasi-first-order kinetic model. The experiment results of free radical quenching show that the reaction process is controlled by many kinds of free radicals. After repeated use for 3 times, the degradation rate of the catalyst decreased from 91.05% to 85.76%, and recovered to 88.32% after thermal regeneration, showing good repeatability and thermal stability.

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