Hydroxylated Uio-66 Based Quartz Crystal Microbalance Gas Sensor for Carbon Dioxide Detection
DOI:
https://doi.org/10.54097/jf01tw07Keywords:
Metal Organic Framework, Quartz Crystal Microbalance, Carbon Dioxide Gas SensorAbstract
The detection of carbon dioxide (CO2) is crucial for monitoring climate change, ensuring air quality, managing industrial processes, and safeguarding human health. However, the chemical inertness and stability of CO2 pose significant challenges to the advancement of detection technologies. To address this, a pre-synthetic modification strategy was employed to introduce hydroxyl (–OH) groups into UiO-66, resulting in the successful preparation of hydroxyl-functionalized UiO-66 for effective CO2 detection. Sensing results demonstrated that, compared with pristine UiO-66, the quartz crystal microbalance (QCM) CO2 sensor based on hydroxyl-functionalized UiO-66 exhibited enhanced gas sensing performance, including a sensitivity of 40.3 Hz to 1000 ppm CO2, response/recovery times of 55 s/58 s, and good selectivity at room temperature.
Downloads
References
[1] E. F. Paiva, J. H. Paxton, and B. J. O'Neil, "The use of end-tidal carbon dioxide (ETCO2) measurement to guide management of cardiac arrest: A systematic review," Resuscitation, vol. 123, pp. 1-7, Feb 2018, doi: 10.1016/j.resuscitation.2017.12.003.
[2] J. Jouwena, D. Verbeke, A. M. De Wolf, A. Neyrinck, and J. F. A. Hendrickx, “In Vitro Model of Prepacked Carbon Dioxide Absorber Use: Development and Testing,” Anesthesiology, vol. 140, no. 3, pp. 450-462, Mar, 2024.
[3] K. Azuma, N. Kagi, U. Yanagi, and H. Osawa, “Effects of low-level inhalation exposure to carbon dioxide in indoor environments: A short review on human health and psychomotor performance,” Environment International, vol. 121, pp. 51-56, Dec, 2018.
[4] L. M. Jablonski, X. Z. Wang, and P. S. Curtis, “Plant reproduction under elevated CO2 conditions: a meta-analysis of reports on 79 crop and wild species,” New Phytologist, vol. 156, no. 1, pp. 9-26, Oct, 2002.
[5] S. Devi, and N. Gupta, “Dynamics of carbon dioxide gas (CO2): Effects of varying capability of plants to absorb CO2,” Natural Resource Modeling, vol. 32, no. 1, pp. 18, Feb, 2019.
[6] X. K. Wang, X. Y. Xu, T. T. Zhou, and T. Zhang, “Nanoscale MOF-74-based QCM gas sensor for CO2 detection at room temperature,” Sensors and Actuators B-Chemical, vol. 413, pp. 11, Aug, 2024.
[7] A. Alassi, M. Benammar, and D. Brett, “Quartz Crystal Microbalance Electronic Interfacing Systems: A Review,” Sensors, vol. 17, no. 12, pp. 41, Dec, 2017.
[8] S. S. Chen, J. Liu, Y. F. Xu, Z. Li, T. Wang, J. Xu, and Z. Wang, “Hydrogen storage properties of the novel crosslinked UiO-66-(OH)2,” International Journal of Hydrogen Energy, vol. 43, no. 32, pp. 15370-15377, Aug, 2018.
[9] F. Sánchez, M. Gutiérrez, and A. Douhal, “Taking Advantage of a Luminescent ESIPT-Based Zr-MOF for Fluorochromic Detection of Multiple External Stimuli: Acid and Base Vapors, Mechanical Compression, and Temperature,” Acs Applied Materials & Interfaces, vol. 15, no. 48, pp. 56587-56599, Nov, 2023.
[10] J. J. Gassensmith, H. Furukawa, R. A. Smaldone, R. S. Forgan, Y. Y. Botros, O. M. Yaghi, and J. F. Stoddart, “Strong and Reversible Binding of Carbon Dioxide in a Green Metal-Organic Framework,” Journal of the American Chemical Society, vol. 133, no. 39, pp. 15312-15315, Oct, 2011.
[11] G. Y. Zhang, G. F. Wei, Z. P. Liu, S. R. J. Oliver, and H. H. Fei, “A Robust Sulfonate-Based Metal-Organic Framework with Permanent Porosity for Efficient CO2 Capture and Conversion,” Chemistry of Materials, vol. 28, no. 17, pp. 6276-6281, Sep, 2016.
[12] N. Mosca, R. Vismara, J. A. Fernandes, G. Tuci, C. Di Nicola, K. V. Domasevitch, C. Giacobbe, G. Giambastiani, C. Pettinari, M. Aragones-Anglada, P. Z. Moghadam, D. Fairen-Jimenez, A. Rossin, and S. Galli, “Nitro-functionalized Bis(pyrazolate) Metal-Organic Frameworks as Carbon Dioxide Capture Materials under Ambient Conditions,” Chemistry-a European Journal, vol. 24, no. 50, pp. 13170-13180, Sep, 2018.
[13] R. A. Smaldone, R. S. Forgan, H. Furukawa, J. J. Gassensmith, A. M. Z. Slawin, O. M. Yaghi, and J. F. Stoddart, “Metal-Organic Frameworks from Edible Natural Products,” Angewandte Chemie-International Edition, vol. 49, no. 46, pp. 8630-8634, 2010.
[14] C. E. Bien, K. K. Chen, S. C. Chien, B. R. Reiner, L. C. Lin, C. R. Wade, and W. S. W. Ho, “Bioinspired Metal-Organic Framework for Trace CO2 Capture,” Journal of the American Chemical Society, vol. 140, no. 40, pp. 12662-12666, Oct, 2018.
[15] V. B. López-Cervantes, E. Sánchez-González, T. Jurado-Vázquez, A. Tejeda-Cruz, E. González-Zamora, and I. A. Ibarra, “CO2 adsorption under humid conditions: Self-regulated water content in CAU-10,” Polyhedron, vol. 155, pp. 163-169, Nov, 2018.
[16] H. Wu, Y. S. Chua, V. Krungleviciute, M. Tyagi, P. Chen, T. Yildirim, and W. Zhou, “Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal-Organic Framework UiO-66 and Their Important Effects on Gas Adsorption,” Journal of the American Chemical Society, vol. 135, no. 28, pp. 10525-10532, Jul, 2013.
[17] S. K. Xian, J. J. Peng, Z. J. Zhang, Q. B. Xia, H. H. Wang, and Z. Li, “Highly enhanced and weakened adsorption properties of two MOFs by water vapor for separation of CO2/CH4 and CO2/N<2 binary mixtures,” Chemical Engineering Journal, vol. 270, pp. 385-392, Jun, 2015.
[18] D. S. Li, W. T. Liu, B. Y. Zhu, M. J. Qu, Q. Zhang, Y. Q. Fu, and J. Xie, “Machine Learning-Assisted Multifunctional Environmental Sensing Based on a Piezoelectric Cantilever,” Acs Sensors, pp. 11, 2022 Sep, 2022.
[19] K. S. Pasupuleti, M. Reddeppa, S. S. Chougule, N. H. Bak, D. J. Nam, N. Jung, H. D. Cho, S. G. Kim, and M. D. Kim, “High performance langasite based SAW NO2 gas sensor using 2D g-C3N4@TiO2 hybrid nanocomposite,” Journal of Hazardous Materials, vol. 427, pp. 12, Apr, 2022.
Downloads
Published
Issue
Section
License
Copyright (c) 2025 Academic Journal of Science and Technology

This work is licensed under a Creative Commons Attribution 4.0 International License.








