Application of Electrochemical Technology in Circulating Cooling Water Treatment for Thermal Power Plants
DOI:
https://doi.org/10.54097/qgv1x012Keywords:
Thermal power plant; Circulating cooling water; Electrochemical treatment; Descaling; Sterilization and algae removal; Water saving and emission reduction.Abstract
Circulating cooling water systems are crucial auxiliary systems in thermal power plants, and their stable operation is essential for ensuring the safe and efficient production of power generating units. Traditional chemical dosing methods, while offering some degree of control over scaling, corrosion, and biofouling, are increasingly limited by their high costs, secondary pollution, and limited effectiveness in removing hardness ions. Electrochemical treatment technology, by creating a highly alkaline environment at the cathode, precipitates hardness ions at the source. Simultaneously, it generates strong oxidizing agents at the anode to kill bacteria and algae. In practice, this technology effectively increases the concentration ratio of circulating cooling water, significantly reduces sewage discharge, and can completely replace chemical agents. It offers significant advantages in water conservation, emission reduction, and green operation. This study focuses on the main principles, key component design, and influencing factors of electrochemical technology. Based on empirical applications in typical thermal power plants, its economic and environmental benefits are analyzed and summarized. The results show that the use of this technology can increase the concentration ratio of circulating cooling water to more than 7 times, save more than 500,000 tons of water annually, and has a short payback period on investment. It has broad application prospects in thermal power generation and other industrial fields.
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[1] He C F, Xiao N, Li J, et al. Research progress on electrochemical treatment technology of circulating cooling water. Industrial Water Treatment. 2022, Vol. 42 (No. 12), p. 26-33.
[2] Cai S J, Zhao X Y, Wang Y Y. Research progress on water-saving technology of circulating cooling water. Industrial Water Treatment. 2009, Vol. 29 (No. 1), p. 4-8.
[3] Hu C Y. Research progress on scale inhibition methods for circulating cooling water in thermal power plants. Guangzhou Chemical Industry. 2017, Vol. 45 (No. 24), p. 53-54, 90.
[4] Xiong F, Yang H, Jin X R. Optimization of makeup water quality and system operation scheme for steel circulating water. Industrial Water Treatment. 2024, Vol. 44 (No. 1), p. 207-212.
[5] Yu X B, Hu D L, Fang L, et al. Transformation scheme and economic analysis of water resource utilization and pollution prevention in a thermal power plant. Industrial Water Treatment. 2023, Vol. 43 (No. 10), p. 179-184.
[6] Zhang N, Cao L, Geng C Z. Research progress on scale inhibitors for circulating water. Modern Chemical Industry. 2015, Vol. 35 (No. 10), p. 54-57, 59.
[7] Su Y, Yang Y, Gu K Y, et al. Research progress on electrochemical descaling technology for circulating cooling water systems. Industrial Water Treatment. 2023, Vol. 43 (No. 8), p. 30-37.
[8] Shen S Y, Feng X D, Shi G Z. Feasibility study on the application of electroadsorption technology in circulating cooling water treatment of thermal power plants. Zhejiang Electric Power. 2015, Vol. 34 (No. 11), p. 89-91, 99.
[9] Wang C C, Shi J, Xiao B Y. Principle and application of electrochemical circulating water quality stabilization treatment technology. Baosteel Technology. 2012, Vol. 2012 (No. 2), p. 63-67.
[10] Jaouhari R, Benbachir A, Guenbour A, et al. Influence of Water Composition and Substrate on Electrochemical Scaling. Journal of The Electrochemical Society. 2000, Vol. 147 (No. 6), p. 2151.
[11] Li S, Wang H F. Application of electrochemical method in cooling circulating water treatment technology. Chemical Industry and Engineering Progress. 2013, Vol. 32 (No. 10), p. 2514-2517.
[12] Song G G. Research progress on chloride ion removal technology in industrial wastewater. Energy Chemical Industry. 2023, Vol. 44 (No. 5), p. 22-26.
[13] Zhi D, Zhang J, Wang J, et al. Electrochemical treatments of coking wastewater and coal gasification wastewater with Ti/Ti4O7 and Ti/RuO2-IrO2 anodes. Journal of Environmental Management. 2020, Vol. 265, p. 110571.
[14] Li Y N, Zhuang X Y, Li H Y, et al. Fabrication and Water Treatment Application of High Efficient PbO2 Electrode. Key Engineering Materials. 2017, Vol. 727, p. 821-829.
[15] Li H Y, Yuan J Q, Li P, et al. Experimental study on reducing circulating water hardness by electrochemical water treatment technology. Water Treatment Technology. 2024, Vol. 50 (No. 3), p. 37-41, 47.
[16] Hu C Z, Liu H J, Qu J H. Research progress in electrochemical water treatment technology. Chinese Journal of Environmental Engineering. 2018, Vol. 12 (No. 3), p. 677-696.
[17] Guo Y, Xu Z, Guo S, et al. Selection of anode materials and optimization of operating parameters for electrochemical water descaling. Separation and Purification Technology. 2021, Vol. 261, p. 118304.
[18] Dube A, Malode S J, Alshehri M A, et al. Electrochemical water treatment: Review of different approaches. Journal of Environmental Management. 2025, Vol. 373, p. 123911.
[19] Liang S T, Lin H, Habteselassie M, et al. Electrochemical inactivation of bacteria with a titanium sub-oxide reactive membrane. Water Research. 2018, Vol. 145, p. 172-180.
[20] Chen L, Zhao B H, Hu Y Y, et al. Pilot-scale experimental study on treatment of circulating water by electrochemical coupling method. Thermal Power Generation. 2025, Vol. 54 (No. 3), p. 158-166.
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