Experimental Study of a Schiff Base as Corrosion Inhibitor for Mild Steel in 1M HCl
DOI:
https://doi.org/10.54097/4zc1ht86Keywords:
Salicylaldehyde ethylenediamine, double Schiff base, corrosion inhibitor, mild steel.Abstract
In this paper, salicylaldehyde ethylenediamine Schiff base (SESB) was prepared by reaction of salicylaldehyde and ethylenediamine at 60℃ for 4 h. The structure of SESB was characterized by hydrogen magnetic resonance spectroscopy. The corrosion inhibition effect of SESB on mild steel in 1mol L-1HCl was studied by weight loss method and electrochemical method. The results showed that the corrosion inhibition effect of SESB on mild steel at 1mol L-1 HCl was negatively correlated with the test temperature at 25℃ to 45℃, and positively correlated with the concentration of SESB at 0mmol L-1 to 5mmol L-1. The results showed that the maximum corrosion inhibition efficiency of SESB at 25℃, 30℃, 35℃, 40℃ and 45℃ were 70.73%, 58.42%, 54.68%, 37.73% and 25.12%, respectively. The results of electrochemical impedance test and electrochemical polarization test show that SESB can not only inhibit the anode metal dissolution of mild steel in 1mol L-1 HCl, but also inhibit the cathode hydrogen precipitation, which is a mixed corrosion inhibitor.
Downloads
References
[1] El Azzouzi, M., Azzaoui, K., Warad, I., Hammouti, B., Shityakov, S., Sabbahi, R., ... & Zarrouk, A. (2022). Moroccan, Mauritania, and senegalese gum Arabic variants as green corrosion inhibitors for mild steel in HCl: Weight loss, electrochemical, AFM and XPS studies. Journal of Molecular liquids, 347, 118354.
[2] Kumar, H., & Dhanda, T. (2021). Cyclohexylamine an effective corrosion inhibitor for mild steel in 0.1 N H2SO4: experimental and theoretical (molecular dynamics simulation and FMO) study. Journal of Molecular Liquids, 327, 114847.
[3] Hegazy, M. A., El-Tabei, A. S., Bedair, A. H., & Sadeq, M. A. (2015). Synthesis and inhibitive performance of novel cationic and gemini surfactants on carbon steel corrosion in 0.5 M H₂SO₄ solution.
[4] Jeeva, M., Prabhu, G. V., Boobalan, M. S., & Rajesh, C. M. (2015). Interactions and inhibition effect of urea-derived Mannich bases on a mild steel surface in HCl. The Journal of Physical Chemistry C, 119(38), 22025-22043.
[5] Murthy, R., Gupta, P., & Sundaresan, C. N. (2020). Theoretical and electrochemical evaluation of 2-thioureidobenzheteroazoles as potent corrosion inhibitors for mild steel in 2 M HCl solution. Journal of Molecular Liquids, 319, 114081.
[6] Golchinvafa, A., Anijdan, S. M., Sabzi, M., & Sadeghi, M. (2020). The effect of natural inhibitor concentration of Fumaria officinalis and temperature on corrosion protection mechanism in API X80 pipeline steel in 1 M H2SO4 solution. International Journal of Pressure Vessels and Piping, 188, 104241.
[7] Bedair, M. A., El-Sabbah, M. M. B., Fouda, A. S., & Elaryian, H. M. (2017). Synthesis, electrochemical and quantum chemical studies of some prepared surfactants based on azodye and Schiff base as corrosion inhibitors for steel in acid medium. Corrosion science, 128, 54-72.
[8] Kalaiselvi, P., Chellammal, S., Palanichamy, S., & Subramanian, G. (2010). Artemisia pallens as corrosion inhibitor for mild steel in HCl medium. Materials Chemistry and Physics, 120(2-3), 643-648.
[9] Fakhry, H., El Faydy, M., Benhiba, F., Laabaissi, T., Bouassiria, M., Allali, M., ... & Zarrouk, A. (2021). A newly synthesized quinoline derivative as corrosion inhibitor for mild steel in molar acid medium: Characterization (SEM/EDS), experimental and theoretical approach. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 610, 125746.
[10] Ehsani, A., Mahjani, M. G., Moshrefi, R., Mostaanzadeh, H., & Shayeh, J. S. (2014). Electrochemical and DFT study on the inhibition of 316L stainless steel corrosion in acidic medium by 1-(4-nitrophenyl)-5-amino-1 H-tetrazole. RSC Advances, 4(38), 20031-20037.
[11] Fernandes, C. M., Alvarez, L. X., dos Santos, N. E., Barrios, A. C. M., & Ponzio, E. A. (2019). Green synthesis of 1-benzyl-4-phenyl-1H-1, 2, 3-triazole, its application as corrosion inhibitor for mild steel in acidic medium and new approach of classical electrochemical analyses. Corrosion Science, 149, 185-194.
[12] Lgaz, H., Salghi, R., & Ali, I. H. (2018). Corrosion inhibition behavior of 9-hydroxyrisperidone as a green corrosion inhibitor for mild steel in hydrochloric acid: electrochemical, DFT and MD simulations studies. International Journal of Electrochemical Science, 13(1), 250-264.
[13] Pandey, A., Singh, B., Verma, C., & Ebenso, E. E. (2017). Synthesis, characterization and corrosion inhibition potential of two novel Schiff bases on mild steel in acidic medium. RSC advances, 7(74), 47148-47163.
[14] Gupta, R. K., Malviya, M., Verma, C., & Quraishi, M. A. (2017). Aminoazobenzene and diaminoazobenzene functionalized graphene oxides as novel class of corrosion inhibitors for mild steel: experimental and DFT studies. Materials Chemistry and Physics, 198, 360-373.
[15] Murmu, M., Saha, S. K., Murmu, N. C., & Banerjee, P. (2019). Effect of stereochemical conformation into the corrosion inhibitive behaviour of double azomethine based Schiff bases on mild steel surface in 1 mol L− 1 HCl medium: An experimental, density functional theory and molecular dynamics simulation study. Corrosion Science, 146, 134-151.
[16] Erami, R. S., Amirnasr, M., Meghdadi, S., Talebian, M., Farrokhpour, H., & Raeissi, K. (2019). Carboxamide derivatives as new corrosion inhibitors for mild steel protection in hydrochloric acid solution. Corrosion Science, 151, 190-197.
[17] Heydari, H., Talebian, M., Salarvand, Z., Raeissi, K., Bagheri, M., & Golozar, M. A. (2018). Comparison of two Schiff bases containing O-methyl and nitro substitutes for corrosion inhibiting of mild steel in 1 M HCl solution. Journal of Molecular liquids, 254, 177-187.
[18] Talebian, M., Raeissi, K., Atapour, M., Fernández-Pérez, B. M., Salarvand, Z., Meghdadi, S., ... & Souto, R. M. (2018). Inhibitive effect of sodium (E)-4-(4-nitrobenzylideneamino) benzoate on the corrosion of some metals in sodium chloride solution. Applied Surface Science, 447, 852-865.
[19] Dueke Eze, C. U., Madueke, N. A., Iroha, N. B., Maduelosi, N. J., Nnanna, L. A., Anadebe, V. C., & Chokor, A. A. (2022). Adsorption and inhibition study of N-(5-methoxy-2-hydroxybenzylidene) isonicotinohydrazide Schiff base on copper corrosion in 3.5% NaCl. Egyptian Journal of Petroleum, 31(2), 31-37.
Downloads
Published
Issue
Section
License
Copyright (c) 2024 Academic Journal of Science and Technology

This work is licensed under a Creative Commons Attribution 4.0 International License.








