Study on Performance and Preparation of Lanthanum-Strontium-Iron-Chromium Electrodes for Using in Symmetric SOFC
DOI:
https://doi.org/10.54097/8d6pg665Keywords:
Symmetric Solid Oxide Fuel Cells, Electrochemical Properties, Fuel Cell, Stability TestingAbstract
Solid oxide fuel cells (SOFCs) is a transformative energy conversion technology that offers higher efficiency, reliability and environmental friendliness compared to conventional systems. In this study, La0.3Sr0.7Cr0.3Fe0.7O3-δ (LSFCr) was prepared by a sol-gel synthesis route and subsequently applied to a symmetric solid oxide fuel cells (SSOFCs). The LSFCr crystal structure was analyzed by X-ray diffraction (XRD) analysis. In order to reduce the manufacturing cost and simplify the cell structure, the SSOFCs configuration LSFCr|SDC|SSZ|SDC|LSFCr (with SDC buffer layer) - was designed using LSTF electrodes, SDC and SSZ electrolytes. The cell has an Rp of 0.7 Ω cm2 and a PPD of 200 mW cm-2 at 800 °C. Notably, the symmetric cell demonstrated robust stability over five redox cycles and maintained performance integrity in short-term durability evaluations, underscoring its potential to advance SSOFCs technology.
Downloads
References
[1] Wang C, Xu Z, Koeppel B. A discrete element model simulation of structure and bonding at interfaces between cathode and cathode contact paste in solid oxide fuel cells. Renewable Energy. 2020; 157:998-1007.
[2] Lu Y, Cai Y, Souamy L, Song X, Zhang L, Wang J. Solid oxide fuel cell technology for sustainable development in China: An over-view. International Journal of Hydrogen Energy. 2018; 43(28):12870-12891.
[3] Mahato N, Banerjee A, Gupta A, Omar S, Balani K. Progress in material selection for solid oxide fuel cell technology: A review. Progress in Materials Science. 2015; 72:141-337.
[4] Zhang P, Huang Y H, Cheng J G, Mao Z Q, Goodenough J B. Sr2CoMoO6 anode for solid oxide fuel cell running on H2 and CH4 fuels. Journal of Power Sources. 2011; 196(4):1738-1743.
[5] Zheng Y, Zhang C, Ran R, Cai R, Shao Z, Farrusseng D. A new symmetric solid-oxide fuel cell with La0.8Sr0.2Sc0.2Mn0.8O3-δ perovskite oxide as both the anode and cathode[J]. Acta Materialia. 2009, 57(4): 1165-1175.
[6] Zhang P, Guan G, Khaerudini DS, Hao X, Han M, Kasai Y, Sasagawa K, Abudula A. Properties of A-site nonstoichiometry (Pr0.4)x Sr0.6Co0.2Fe0.7Nb0.1O3-δ(0.9≤ x≤ 1.1) as symmetrical electrode material for solid oxide fuel cells[J]. Journal of Power Sources. 2014, 248: 163-171.
[7] Ruiz-Morales J C, Canales-Vázquez J, Peña-Martínez J, López DM, Núñez P. On the simultaneous use of La0.75Sr0.25Cr0.5Mn0.5O3−δ as both anode and cathode material with improved microstructure in solid oxide fuel cells[J]. Electrochimica Acta. 2006, 52(1): 278-284.
[8] Wei T, Zhou X, Hu Q, Gao Q, Han D, Lv X, Wang S. A high power density solid oxide fuel cell based on nano-structured La0.8Sr0.2Cr0.5Fe0.5O3-δ anode[J]. Electrochimica Acta. 2014, 148: 33-38.
[9] Luo T, Liu X, Meng X, Wu H, Wang S, Zhan Z. In situ formation of LaNi0.6Fe0.4O3−δ–carbon nanotube hybrids as anodes for direct-methane solid oxide fuel cells[J]. Journal of Power Sources. 2015, 299: 472-479
[10] Liu X, Han D, Zhou Y, Meng X, Wu H, Li J, Zeng F, Zhan Z. Sc-substituted La0.6Sr0.4FeO3−δ mixed conducting oxides as promising electrodes for symmetrical solid oxide fuel cells[J]. Journal of Power Sources. 2014, 246: 457-463.
[11] Canales-Vázquez J, Ruiz-Morales JC, Marrero-López D, Peña-Martínez J, Núñez P, Gómez-Romero P. Fe-substituted (La,Sr)TiO3 as potential electrodes for symmetrical fuel cells (SFCs)[J]. Journal of Power Sources. 2007, 171(2): 552-557.
[12] Fan W, Sun Z, Bai Y, Wu K, Cheng Y. Highly stable and efficient perovskite ferrite electrode for symmetrical solid oxide fuel cells[J]. ACS applied materials & interfaces. 2019, 11(26): 23168-23179.
Downloads
Published
Issue
Section
License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.