Application research of MOF and its Ni-doping materials in supercapacitor
DOI:
https://doi.org/10.54097/hset.v13i.1352Keywords:
Pseudocapacitor; MOF-5 materials; Ni-MOF-5 composites; Specific capacitance.Abstract
With the development of the technology and the automation of the modern industry, finding a new kind of energy storing device gradually occupies a significant position. The supercapacitor takes up scientists’ eyes, because of its advantages of high watt density, long servicing life and non-pollution. However, there is also some barriers blocking the way of the forward development. In this project, we use MOF-5 as the electrode material, combining with some other metal atoms to enhance its specific capacitance. Through researching, we found that using Ni as the adding atom has a markable difference. It can improve the conductivity of the electrode effectively, then enhancing the specific capacitance. Finally, we measured the data of the supercapacitor using Ni-MOF-5 as the electrode materials under different scanning speed. Then we got the specific capacitance respectively: 105 under 50 , 78 under 100 , 44 under 500 , 35 under 1000 .
Downloads
References
Wojciech Kukulka and Krzysztof Cendrowski and Ewa Mijowska. Electrochemical performance of MOF-5 derived carbon nanocomposites with 1D, 2D and 3D carbon structures[J]. Electrochimica Acta, 2019, 307 : 582-594.
Ji Junyi et al. Advanced Graphene-Based Binder-Free Electrodes for High-Performance Energy Storage. [J]. Advanced materials (Deerfield Beach, Fla.), 2015, 27(36) : 5264-79.
Kishore babu S et al. Metal-organic framework (MOF-5) incorporated on NiCo2O4 as electrode material for supercapacitor application[J]. Materials Letters, 2021, 302
Yuan Jiashu et al. Highly selective metal-organic framework-based (MOF-5) separator for non-aqueous redox flow battery[J]. Chemical Engineering Journal, 2022, 433(P2)
Lu Xianlu et al. MOF-5 as anodes for high-temperature potassium-ion batteries with ultrahigh stability[J]. Chemical Engineering Journal, 2022, 432
Jia Dandan et al. BN nanosheets in-situ mosaic on MOF-5 derived porous carbon skeleton for high-performance lithium-ion batteries[J]. Journal of Alloys and Compounds, 2020, : 157571-.
Aldroubi Soha et al. When graphene meets ionic liquids: a good match for the design of functional materials.[J]. Nanoscale, 2021, 13(5) : 2750-2779.
Takanori Fukushima et al. Molecular Ordering of Organic Molten Salts Triggered by Single-Walled Carbon Nanotubes[J]. Science, 2003, 300(5628) : 2072-2074.
Meltem Tunckol and Jérôme Durand and Philippe Serp. Carbon nanomaterial–ionic liquid hybrids[J]. Carbon, 2012, 50(12) : 4303-4334.
Sedahmed Osman et al. Highly activated porous carbon with 3D microspherical structure and hierarchical pores as greatly enhanced cathode material for high-performance supercapacitors[J]. Journal of Power Sources, 2018, 391 : 162-169.
Xinlong Yan et al. Porous carbons prepared by direct carbonization of MOFs for supercapacitors[J]. Applied Surface Science, 2014, 308 : 306-310.
Moxin Yu et al. 3D interconnected porous carbons from MOF-5 for supercapacitors[J]. Materials Letters, 2016, 172 : 81-84.
Avery E. Baumann et al. Metal-organic framework functionalization and design strategies for advanced electrochemical energy storage devices[J]. Communications Chemistry, 2019, 2(1) : 1-14.
Lan Wang et al. “Brick-and-mortar” sandwiched porous carbon building constructed by metal-organic framework and graphene: Ultrafast charge/discharge rate up to 2 V s−1 for supercapacitors[J]. Nano Energy, 2016, 30 : 84-92.
Bo Liu et al. Metal–organic framework (MOF) as a template for syntheses of nanoporous carbons as electrode materials for supercapacitor[J]. Carbon, 2009, 48(2) : 456-463.
Downloads
Published
Issue
Section
License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.







