Study of Cathode Oxygen Reduction Reaction (ORR) Catalysts for Proton Exchange Membrane Fuel Cells (PEMFCs)
DOI:
https://doi.org/10.54097/hv1e3j68Keywords:
Electrochemical technology, PEMFCs, non-metal catalysts, metal catalysts, non-precious metal catalysts.Abstract
With the increasing depletion of non-renewable energy sources, more and more attention is being paid to the development of sustainable energy sources. The paper outlines the fundamental ideas behind oxygen reduction reaction (ORR) catalysts and proton exchange membrane fuel cells (PEMFCs), discusses the various types of ORR catalysts, and examines the limitations of this technology. In this paper, three types of ORR catalysts, metal catalysts, non-precious metal catalysts, and non-metal catalysts, are introduced in turn, and the pros and cons of the three types of ORR catalysts are analysed. Among them, metal catalysts possess advantages such as high efficiency and controllability, but are expensive and difficult to commercialise widely. The second type of catalyst is usually made from more common and cheaper metals and is therefore less expensive to produce. However, the catalytic activity is lower, resulting in a slower reaction rate and therefore a higher amount of catalyst is required. Non-metallic catalysts are usually not dependent on rare metal resources and are therefore relatively low cost. In addition, non-metallic catalysts offer higher selectivity and controllability, but lower catalytic rates. This paper expects that with the growth of the hydrogen energy industry, proton exchange membrane fuel cells will gradually be widely used in the fields of transport and power supply, providing a cleaner and more efficient energy source for human beings.
Downloads
References
Molaeimanesh G.R., Torabi F., Chapter 1 - Fuel cell fundamentals. In: Molaeimanesh, G. R., Torabi F. (Eds.), Fuel Cell Modeling and Simulation. Elsevier Inc., Tehran. 2023, 1 - 56.
Sharma P., Pandey, O.P., Chapter 1 - Proton exchange membrane fuel cells: fundamentals, advanced technologies, and practical applications. In: Kaur, G. (Ed.), PEM Fuel Cells. Elsevier Inc., Patiala. 2022, 1 - 24.
Janssen M., Weber P., Oezaslan M., Recent advances of various Pt-based catalysts for oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cells (PEMFCs). Current Opinion in Electrochemistry, 2023, 40, 101337.
Tao J., Wang X., Xu M., Liu C., Ge J., Xing W., Non-noble metals as activity sites for ORR catalysts in proton exchange membrane fuel cells (PEMFCs). Industrial Chemistry & Materials, 2023, 2: 149 - 273.
Reshetenko T.V., Serov A., Odgaard M., Randolf G., Osmieri L., Kulikovsky A., Electron and proton conductivity of Fe-N-C cathodes for PEM fuel cells: A model-based electrochemical impedance spectroscopy measurement. Electrochemistry Communications, 2020, 118: 106795 – 106795.
Cheng Q., Han S., Mao K., Chen C., Yang L., Zou Z., et al., Co nanoparticle embedded in atomically-dispersed Co-N-C nanofibers for oxygen reduction with high activity and remarkable durability. Nano Energy, 2018, 52: 485 – 493.
Moghaddam M.S., Bahari A., Litkohi H.R., Using the synergistic effects of MoS2/rGO and bimetallic hybrids as a high-performance nanoelectrocatalyst for oxygen reduction reaction. International Journal of Hydrogen Energy, 2023.
Ding J., Wang H., Yang X., Ju W., Shen K., Chen L., Li Y., A Janus heteroatom-doped carbon electrocatalyst for hydrazine oxidation. National Science Review, 2023, 10 (3).
Öztürk A., Yurtcan, A.B., Synthesis of polypyrrole (PPy) based porous N-doped carbon nanotubes (N-CNTs) as catalyst support for PEM fuel cells. International Journal of Hydrogen Energy, 2018, 43 (40): 18559 – 18571.
Al-Gamal A.G., Chowdhury T.H., Kabel K.I., Farag A.A., Rabie A.M., et al., Promising Nitrogen-Doped Graphene Derivatives; A Case Study for Preparations, Fabrication Mechanisms, and Applications in Perovskite Solar Cells. Topics in Current Chemistry, 2022, 381 (1).
Stephan O., Ajayan P.M., Colliex C., Redlich P., Lambert J.M., Bernier P., Lefin P., Doping Graphitic and Carbon Nanotube Structures with Boron and Nitrogen. Science, 1994, 266 (5191): 168 3 – 1685.
Denis P. A., Faccio R., Mombru A.W., Is It Possible to Dope Single-Walled Carbon Nanotubes and Graphene with Sulfur? ChemPhysChem, 2009, 10 (4): 715 – 722.
Zhou Y., Zhu Y., Lin S., Li K., Xue D., Synthesis of Sulfur-Doped Carbon Nanotubes by Liquid Precursor. Materials Focus, 2013, 2 (1): 44 – 47.
Downloads
Published
Issue
Section
License
Copyright (c) 2024 Highlights in Science, Engineering and Technology

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.







