Research Progress in Magnesium-Based Solid Hydrogen Storage
DOI:
https://doi.org/10.54097/8ezm5q10Keywords:
solid hydrogen storage, MgH2, magnesium-based hydrogen storage material, hydrogen absorption, discharge performance.Abstract
The materials produced with magnesium for hydrogen storage have the highest potential for growth and have received huge attention because of their low cost, large supply, and excellent hydrogen storage capacity. However, because to its steady hydrogen absorption and emission thermodynamics and slow kinetics, this material's use in hydrogen storage is constrained. Hydrogen uptake and release of materials are thermodynamically stable and slow kinetic, because hydrogen molecules have a high dissociation energy on the surface of Mg, while hydrogen atoms have a slow diffusion rate in the magnesium lattice, which limits its application. Therefore, a large number of research works have focused on the thermal/kinetic modification of magnesium-based materials recently, and has made significant progress. In this paper, the modification methods of the above materials are analyzed, with emphasis on the mechanism of absorption and release of hydrogen, and the influence of alloying, nano crystallization and catalyst addition on optimizing and improving the material properties. Finally, research results are summarized, and the future development direction is discussed.
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References
Schlapbach L, Züttel A. Hydrogen-storage materials for mobile applications. Nature, 2001, 414: 353 – 358.
Wei Zheng. The possibility of hydrogen energy replacing the petroleum energy industry [J]. China Petroleum and Chemical Industry Standards and Quality, 2022, 42 (04): 125 - 127. 3.
LEE SeulYi, LEE JongHoon, KIM YeongHun, et al. Recent progress using solid-state materials for hydrogen storage: A short review [J]. Processes, 2022, 10 (2): 304.
BARDHAN Rizia, RUMINSKI Anne M, BRAND Alyssa, et al. Magnesium nanocrystal-polymer composites: A new platform for designer hydrogen storage materials [J]. Energy & Environmental Science, 2011, 4 (12): 4882 - 4895.
STAMPFER J F Jr, HOLLEY C E Jr, SUTTLE J F. The magnesium-hydrogen System 1-3 [J]. Journal of the American Chemical Society, 1960, 82 (14): 3504 - 3508.
BOHMHAMMEL K, WOLF U, WOLF G, et al. Thermodynamic optimization of the system magnesium-hydrogen[J]. Thermochemical Acta, 1999, 337 (1/2): 195 - 199.
Zhang Q Y, Du S C, Ma Z W, et al. Recent advances in Mg-based hydrogen storage materials (in Chinese). Chin Sci Bull, 2022, 67: 2158 – 2171, doi: 10.1360/TB - 2021 - 0430.
Shi Keke, Liu Muzi, Zhao Qiang, Li Jinping & Liu Guang. Performance and research progress of magnesium-based hydrogen storage materials. Chemical progress. Doi: 10.16085/j.issn.1000 - 6613.2022 - 1905.
Liu T, Zhang T, Zhang X, et al. Synthesis and hydrogen storage properties of ultrafine Mg-Zn particles. Int J Hydrog Energy, 2011, 36: 3515 - 3520.
CUI Jie, LIU Jiangwen, WANG Hui, et al. Mg-TM (TM: Ti, Nb, V, Co, Mo or Ni) core-shell like nanostructures: Synthesis, hydrogen storage performance and catalytic mechanism [J]. Journal of Materials Chemistry A, 2014, 2 (25): 9645 - 9655.
Zou J, Long S, Chen X, et al. Preparation and hydrogen sorption properties of a Ni decorated Mg based Mg@Ni nano-composite. Int J Hydrog Energy, 2015, 40: 1820 - 1828.
Chen M, Pu Y, Li Z, et al. Synergy between metallic components of MoNi alloy for catalyzing highly efficient hydrogen storage of MgH2. Nano Res, 2020, 13: 1 - 9.
Liu G, Wang Y, Jiao L, et al. Solid-state synthesis of amorphous TiB2 nanoparticles on graphene nanosheets with enhanced catalytic dehydrogenation of MgH2. Int J Hydrog Energy, 2014, 39: 3822 - 3829.
Zhang X, Shen Z, Jian N, et al. A novel complex oxide TiVO3.5 as a highly active catalytic precursor for improving the hydrogen storage properties of MgH2. Int J Hydrog Energy, 2018, 43: 23327 - 23335.
LOTOSKYY Mykhaylo, DENYS Roman, YARTYS Volodymyr A, et al. An outstanding effect of graphite in nano-MgH2-TiH2 on hydrogen storage performance [J]. Journal of Materials Chemistry A, 2018, 6 (23): 10740 - 10754.
VAJEESTON P, SARTORI S, RAVINDRAN P, et al. MgH2 in carbon scaffolds: A combined experimental and theoretical investigation [J]. The Journal of Physical Chemistry C, 2012, 116 (40): 21139 - 21147.
LIU Wei, AGUEY-ZINSOU Kondo-Francois. Hydrogen storage properties of in situ stabilised magnesium nanoparticles generated by electroless reduction with alkali metals [J]. International Journal of Hydrogen Energy, 2015, 40 (47): 16948 - 16960.
LIU Wei, AGUEY-ZINSOU Kondo-Francois. Size effects and hydrogen storage properties of Mg nanoparticles synthesized by an electroless reduction method [J]. Journal of Materials Chemistry A, 2014, 2 (25): 9718 - 9726.
SUN Yahui, AGUEY-ZINSOU Kondo-Francois. Synthesis of magnesium nanofibers by electroless reduction and their hydrogen interaction properties [J]. Particle & Particle Systems Characterization, 2017, 34 (4): 1600276.
CHO Eun Seon, RUMINSKI Anne M, ALONI Shaul, et al. Graphene oxide/metal nanocrystal multilaminates as the atomic limit for safe and selective hydrogen storage [J]. Nature Communications, 2016, 7: 10804.
Li W, Li C, Ma H, et al. Magnesium nanowires: Enhanced kinetics for hydrogen absorption and desorption. J Am Chem Soc, 2007, 129: 6710 – 6711.
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