Advances in Sodium-Ion Battery Technology: Enhancing Energy Density for Future Applications
DOI:
https://doi.org/10.54097/62wswy20Keywords:
Sodium-ion battery; anode material; cathode material; electrolyte.Abstract
Achieving high energy density in sodium-ion batteries (SIBs) is crucial for advancing their potential as a substitute for lithium-ion batteries, particularly in large-scale energy storage systems. However, the development of SIBs faces several challenges, including limitations in cathode and anode materials, issues with dendrite formation, low ionic conductivity, and significant electrolyte volume expansion. These barriers directly impact the energy density and overall performance of SIBs. Current research has concentrated on producing cutting-edge anode materials like hard carbon and optimizing cathode materials like layered oxides and polyanionic compounds in order to get over these restrictions. Additionally, advancements in electrolyte formulations are crucial to ensure greater stability and ionic mobility. Emerging technologies, including the use of nanostructured materials and novel cell architectures, have also been explored as potential solutions to enhance energy density. This paper synthesizes these advancements and evaluates the pathways to improving cycle stability, minimizing volumetric changes, and enhancing safety features. With continued research, SIBs could become a key component in future sustainable energy storage solutions, offering cost-effective and high-performance alternatives to existing technologies.
Downloads
References
[1] Zhu Changbao, Kopold Peter, van Aken Peter A., et al. High power-high energy sodium battery based on threefold interpenetrating network. Advanced Materials, 2016, 28(12): 2409-2416. DOI: https://doi.org/10.1002/adma.201505943
[2] Jian Zelang, Zhao Liang, Pan Huilin, et al. Carbon coated Na3V2 (PO4)3 as novel electrode material for sodium ion batteries. Electrochemistry Communications, 2012, 14(1): 86-89. DOI: https://doi.org/10.1016/j.elecom.2011.11.009
[3] Fang Yongjin, Zhang Jiexin, Xiao Lifen, et al. Phosphate framework electrode materials for sodium ion batteries. Advanced Science, 2017, 4(5): 1600392. DOI: https://doi.org/10.1002/advs.201600392
[4] Chen Shuangqiang, Wu Chao, Shen Laifa, et al. Challenges and perspectives for NASICON-type electrode materials for advanced sodium-ion batteries. Advanced Materials, 2017, 29(48): 1700431. DOI: https://doi.org/10.1002/adma.201700431
[5] Yuan Yong, Wei Qingyuan, Yang Shaokang, et al. Towards high-performance phosphate-based polyanion-type materials for sodium-ion batteries. Energy Storage Materials, 2022, 50: 760-782. DOI: https://doi.org/10.1016/j.ensm.2022.06.008
[6] Rajagopalan Ranjusha, Zhang Zhengna, Tang Yougen, et al. Understanding crystal structures, ion diffusion mechanisms and sodium storage behaviors of NASICON materials. Energy Storage Materials, 2021, 34: 171-193. DOI: https://doi.org/10.1016/j.ensm.2020.09.007
[7] Ren Wenhao, Zheng Zhiping, Xu Chang, et al. Self-sacrificed synthesis of three-dimensional Na3V2 (PO4)3 nanofiber network for high-rate sodium–ion full batteries. Nano Energy, 2016, 25: 145-153. DOI: https://doi.org/10.1016/j.nanoen.2016.03.018
[8] Li Hui, Yu Xiqian, Bai Ying, et al. Effects of Mg doping on the remarkably enhanced electrochemical performance of Na3V2(PO4)3 cathode materials for sodium ion batteries. Journal of Materials Chemistry A, 2015, 3(18): 9578-9586. DOI: https://doi.org/10.1039/C5TA00277J
[9] Gao Hongcai, Seymouret Ieuan D., Xin Sen, et al. Na3MnZr (PO4)3: a high-voltage cathode for sodium batteries. Journal of the American Chemical Society, 2018, 140(51): 18192-18199. DOI: https://doi.org/10.1021/jacs.8b11388
[10] Klee Rafael, Maciej Wiatrowski, Aragón María J., et al. Improved surface stability of C+MxOy@Na3v2 (PO4)3 prepared by ultrasonic method as cathode for sodium-ion batteries. ACS Applied Materials & Interfaces, 2017, 9(2): 1471-1478. DOI: https://doi.org/10.1021/acsami.6b12688
[11] Alcántara Ricardo, Pedro Lavela, Ortiz Gregorio F., et al. Electrochemical, textural and microstructural effects of mechanical grinding on graphitized petroleum coke for lithium and sodium batteries. Carbon, 2003, 41(15): 3003-3013. DOI: https://doi.org/10.1016/S0008-6223(03)00432-9
[12] Luo Wei, Jian Zelang, Xing Zhenyu, et al. Electrochemically expandable soft carbon as anodes for Na-ion batteries. ACS Central Science, 2015, 1 (9): 516-522. DOI: https://doi.org/10.1021/acscentsci.5b00329
[13] Jian Zelang, Bommier Clement, Luo Langli, et al. Insights on the mechanism of Na-ion storage in soft carbon anode. Chemistry of Materials, 2017, 29(5): 2314-2320. DOI: https://doi.org/10.1021/acs.chemmater.6b05474
[14] Li Yunming, Hu Yong-Sheng Hu, Qi Xingguo, et al. Advanced sodium-ion batteries using superior low cost pyrolyzed anthracite anode: Towards practical applications. Energy Storage Materials, 2016, 5: 191-197. DOI: https://doi.org/10.1016/j.ensm.2016.07.006
[15] Bai Linyi, Sun Liqun, Wang Yang, et al. Solution-processed black phosphorus/PCBM hybrid heterojunctions for solar cells. Journal of Materials Chemistry A, 2016, 5(18): 8280-8286. DOI: https://doi.org/10.1039/C6TA08140A
[16] Li Wei-Jie, Chou Shu-Lei, Wang Jia-Zhao, et al. A new, cheap, and productive FeP anode material for sodium-ion batteries. Chemical Communications, 2015, 51(17): 3682-3685. DOI: https://doi.org/10.1039/C4CC09604E
[17] Chi Xiaowei, Liang Yanliang, Hao Fang, et al., Tailored organic electrode material compatible with sulfide electrolyte for stable all‐solid‐state sodium batteries. Angewandte Chemie, 2018, 57(10): 2630-2634. DOI: https://doi.org/10.1002/anie.201712895
Downloads
Published
Issue
Section
License
Copyright (c) 2025 Highlights in Science, Engineering and Technology

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.







