Preparation and Application Progress of MOFs
DOI:
https://doi.org/10.54097/pjfw3839Keywords:
MOFs, material structure, synthesis technology, application.Abstract
The everyday needs of humanity can no longer be met by traditional materials due to advancements in science and technology. These days, the main objective is to produce materials with increased usefulness, superior performance, and recyclability. Because of their high specific surface area and porosity, easily functionalizable pore structure, and customizable pore structure, metal-organic skeletons (MOFs) represent a novel class of porous materials with a wide variety of applications in the energy, environment, and biomedical sectors. Therefore, this paper summaries the latest research progress in the study of MOFs. Firstly, the paper introduces the basic features of MOFs, including metal centers and organic ligands, and discusses the tunability of these modules for the geometrical and chemical properties of MOFs. Then, the main synthetic methods of MOFs are summarized, including solvothermal synthesis, electrochemical synthesis, and microbiome-assisted synthesis. Finally, the paper also highlights the applications of MOFs in gas storage/separation, biomedicine, and environmental protection. It aims to provide some reference significance for the future development direction of MOFs.
Downloads
References
De V.T., et al. Principles of design and synthesis of metal derivatives from MOFs. Advanced Materials, 2023: 2210166.
Wang B, et al. A microporous aluminum-based metal-organic framework for high methane, hydrogen, and carbon dioxide storage. Nano Research, 2021, 14: 507-511.
Qazvini OT, et al. Selective capture of carbon dioxide from hydrocarbons using a metal-organic framework. Nature communications, 2021, 12(1): 197.
Fang C, et al. Co–ferrocene MOF/glucose oxidase as cascade nanozyme for effective tumor therapy. Advanced Functional Materials, 2020, 30(16): 1910085.
Geng FL, et al. Stability performance analysis of Fe based MOFs for peroxydisulfates activation to effectively degrade ciprofloxacin. Frontiers in Bioengineering and Biotechnology, 2023, 11.
Ren Q, et al. Preparation of Zr-MOFs for the adsorption of doxycycline hydrochloride from wastewater. Green Processing and Synthesis, 2023, 12(1): 20228127.
Li C, et al. Metal centers and organic ligands determine electrochemistry of metal–organic frameworks. Small, 2022, 18(11): 2106607.
Ma D, et al. Metal-organic frameworks: Synthetic methods for industrial production. Nano Research, 2023, 16(5): 7906-7925.
Hu Z, et al. Modulated hydrothermal synthesis of highly stable MOF-808 (Hf) for methane storage. ACS Sustainable Chemistry & Engineering, 2020, 8(46): 17042-17053.
Ma D, et al. Metal-organic frameworks: Synthetic methods for industrial production. Nano Research, 2023, 16(5): 7906-7925.
Abdel G.H, Abdelhameed R. The chemistry and applications of europium-based metal-organic frameworks (Eu-MOFs). Egyptian Journal of Chemistry, 2023.
He H, et al. Preparation of MOFs and MOFs derived materials and their catalytic application in air pollution: A review. Catalysis Today, 2021, 375: 10-29.
Li H, et al. Porous metal-organic frameworks for gas storage and separation: Status and challenges. EnergyChem, 2019, 1(1): 100006.
Cheng W, et al. Exposing unsaturated Cu1-O2 sites in nanoscale Cu-MOF for efficient electrocatalytic hydrogen evolution. Science Advances, 2021, 7(18): eabg2580.
Downloads
Published
Issue
Section
License
Copyright (c) 2024 Highlights in Science, Engineering and Technology

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.







