Improving Energy Density in Lithium-Ion Batteries Using Nanomaterials
DOI:
https://doi.org/10.54097/nfkgp156Keywords:
Lithium-ion batteries, nanomaterials, nanotechnology.Abstract
Lithium-ion batteries are pivotal in modern energy storage, powering everything from consumer electronics to electric vehicles. Despite their advantages, current materials limit their energy density, particularly for electric vehicles. This paper explores the potential of nanomaterials to enhance lithium-ion battery performance, focusing on anodes, cathodes, and electrolytes. The study discusses the limitations of traditional graphite anodes and highlights nanostructured silicon and metal oxides as alternatives to significantly increase capacity and reduce volume expansion. For cathodes, it examines how nanomaterials like S-TiO2 yolk-shell structures and high-voltage cathode materials can improve energy density and stability. The role of nanostructured solid electrolytes in enhancing ionic conductivity and overall battery performance is also analyzed. The paper addresses the challenges of using nanomaterials, such as higher costs and the need for scalable production methods. It suggests future research directions, including optimizing nanostructures and developing cost-effective manufacturing processes. The findings underscore the potential of nanotechnology to overcome current limitations and significantly boost the energy density of lithium-ion batteries.
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[1] Masias A, Marcicki J, Paxton WA. Opportunities and challenges of lithium-ion batteries in automotive applications. ACS energy letters. 2021; 6 (2): 621-30.
[2] Chen X, Shen W, Vo TT, Cao Z, Kapoor A. An overview of lithium-ion batteries for electric vehicles. In2012 10th International Power & Energy Conference (IPEC) 2012; 230-235. IEEE.
[3] Lu L, Han X, Li J, Hua J, Ouyang M. A review on the key issues for lithium-ion battery management in electric vehicles. Journal of power sources. 2013, 226: 272-88.
[4] Deng J, Bae C, Denlinger A, Miller T. Electric vehicles batteries: requirements and challenges. Joule. 2020; 4 (3): 511-5.
[5] Bruce PG, Scrosati B, Tarascon JM. Nanomaterials for rechargeable lithium batteries. Angewandte Chemie International Edition. 2008; 47 (16): 2930-46.
[6] Lee KT, Cho J. Roles of nanosize in lithium reactive nanomaterials for lithium ion batteries. Nano today. 2011; 6 (1): 28-41.
[7] Jiang C, Hosono E, Zhou H. Nanomaterials for lithium ion batteries. Nano today. 2006; 1 (4): 28-33.
[8] Li M, Lu J, Chen Z, Amine K. 30 years of lithium‐ion batteries. Advanced Materials. 2018; 30 (33): 1800561.
[9] Cao W, Zhang J, Li H. Batteries with high theoretical energy densities. Energy Storage Materials. 2020; 26: 46-55.
[10] Zamfir MR, Nguyen HT, Moyen E, Lee YH, Pribat D. Silicon nanowires for Li-based battery anodes: a review. Journal of Materials Chemistry A. 2013; 1 (34): 9566-86.
[11] L. Y. Beaulieu, K. W. Eberman, R. L. Turner, L. J. Krause and J. R. Dahn, Electrochem. Solid-State Lett., 2001, 4, A137—A140.
[12] L. Y. Beaulieu, T. D. Hatchard, A. Bonakdarpour, M. D. Fleischauer and J. R. Dahn, J. Electrochem. Soc., 2003, 150, A1457—A1465.
[13] J. O. Besenhard, J. Yang and M. Winter, J. Power Sources, 1997, 68, 87—905.
[14] Sun Y, Liu N, Cui Y. Promises and challenges of nanomaterials for lithium-based rechargeable batteries. Nature Energy. 2016; 1 (7): 1-2.
[15] Seh ZW, Li W, Cha JJ, Zheng G, Yang Y, McDowell MT, Hsu PC, Cui Y. Sulphur-TiO2 yolk-shell nanoarchitecture with internal void space for long-cycle lithium-sulphur batteries. Nature communications. 2013; 4: 1331.
[16] Zhou, W. D., Yu, Y. C., Chen, H., DiSalvo, F. J. & Abruña, H. D. Yolk–shell structure of polyaniline-coated sulfur for lithium–sulfur batteries. J. Am. Chem. Soc. 2013,135, 16736–16743
[17] Manthiram A, Yu X, Wang S. Lithium battery chemistries enabled by solid-state electrolytes. Nature Reviews Materials. 2017; 2 (4): 1-6.
[18] Nano-silicon/carbon composite anode materials towards practical application for next generation Li-ion batteries. Journal of The Electrochemical Society. 2015; 162 (14): A2509.
[19] Mehrer, H. Diffusion in Solids: Fundamentals, Methods, Materials, Diffusion-Controlled Luo F, Liu B, Zheng J, Chu G, Zhong K, Li H, Huang X, Chen L.
[20] Wang X, Zhai H, Qie B, Cheng Q, Li A, Borovilas J, Xu B, Shi C, Jin T, Liao X, Li Y. Rechargeable solid-state lithium metal batteries with vertically aligned ceramic nanoparticle/polymer composite electrolyte. Nano Energy. 2019; 60: 205-12.
[21] Wang S, Chen L. Interfacial transport in lithium-ion conductors. Chinese Physics B. 2015; 25 (1): 018202.
[22] Maier J. Defect chemistry: composition, transport, and reactions in the solid state; part I: thermodynamics. Angewandte Chemie International Edition in English. 1993; 32 (3): 313-35.
[23] Liu N, Lu Z, Zhao J, McDowell MT, Lee HW, Zhao W, Cui Y. A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes. Nature nanotechnology. 2014; 9 (3): 187-92.
[24] Bandhauer, T.M.; Garimella, S.; Fuller, T.F. A critical review of thermal issues in lithium-ion batteries. J. Electrochem. Soc. 2011, 158, R1–R25.
[25] Goriparti S, Miele E, De Angelis F, Di Fabrizio E, Zaccaria RP, Capiglia C. Review on recent progress of nanostructured anode materials for Li-ion batteries. Journal of power sources. 2014; 257: 421-43.
[26] Opra DP, Gnedenkov SV, Sinebryukhov SL. Recent efforts in design of TiO2 (B) anodes for high-rate lithium-ion batteries: A review. Journal of Power Sources. 2019; 442: 227225.
[27] Wang X, Wang X, Lu Y. Realizing high voltage lithium cobalt oxide in lithium-ion batteries. Industrial & Engineering Chemistry Research. 2019; 58 (24): 10119-39.
[28] Mladenov M, Stoyanova R, Zhecheva E, Vassilev S. Effect of Mg doping and MgO-sur0face modification on the cycling stability of LiCoO2 electrodes. Electrochemistry Communications. 2001; 3 (8): 410-6.
[29] Liu S, Xiong L, He C. Long cycle life lithium ion battery with lithium nickel cobalt manganese oxide (NCM) cathode. Journal of Power Sources. 2014; 261: 285-91.
[30] Lee KS, Myung ST, Amine K, Yashiro H, Sun YK. Structural and Electrochemical Properties of Layered Li [Ni1− 2x Co x Mn x] O2 (x=0.1–0.3) Positive Electrode Materials for Li-Ion Batteries. Journal of The Electrochemical Society. 2007; 154 (10): A971.
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