Research Progress on Improvement Strategies of Polymer Electrolytes in Solid-State Batteries

Authors

  • Hangyang Zhou

DOI:

https://doi.org/10.54097/fyphrv62

Keywords:

polymer electrolyte, ionic conductivity, mechanical strength.

Abstract

The solid electrolyte material can replace the liquid electrolyte in the lithium-ion batteries, which ensures higher safety due to the flammable and corroded of liquid electrolyte. The polymer electrolytes demonstrated feasibility due to its suitable ductility. However, lithium ions in the polymer electrolytes are more difficult to ionize, resulting in worse ionic conductivity. At the same time, the mechanical strength of polymer electrolytes is not as good as that of inorganic electrolytes, which is not enough to inhibit the penetration of lithium dendrite. To solve these problems, researchers adopt two strategies: adding fillers or reactants and constructing artificial interface layers, focusing on improving ionic conductivity and mechanical strength. Based on the latest research, the problems faced by polymer electrolytes and improvement measures are reviewed, which provide references for the future development of polymer electrolytes.

Downloads

Download data is not yet available.

References

[1] Han Wang, Hanwen An, et al. Research Progress on Interfaces of All-Solid-State Batteries. Acta Physico-Chimica Sinica[J]. 2021, 37(11)

[2] Zhixiang Yuan, Hao Zhang, Sijia Hu, et al. Research Progress of Ion-initiated in situ Generated Solid Polymer Electrolytes for High-safety Lithium Batteries. Acta Chimica Sinica[J]. 2023, 81:1064-1080

[3] Dai Wang, Lei Tian, et al. The Research Progress of Solid Polymer Electrolyt. Polymer Bulletin[J]. 2023, 36(6)

[4] Ramesh S, Lu S C. Enhancement of ionic conductivity and structural properties by BMIMTf ionic liquid in P (VdF-HFP)-based polymer electrolytes. Apply Polymer Sci[J], 2012, 126: 484-492.

[5] Koh Sing Ngai, S. Ramesh, et al. A review of polymer electrolytes: fundamental, approaches and applications. Ionics[J]. 2016, 22:1259-1279

[6] Kim J K, Cheruvally G, Li X, et al. Preparation and electrochemical characterization of electrospun, microporous membrane-based composite polymer electrolytes for lithium batteries. Journal of Power Sources[J]. 2008, 178(2): 815-820.

[7] Ramesh S, Liew C W. Exploration on nano-composite fumed silica-based composite polymer electrolytes with doping of ionic liquid. Journal of Non-crystalline Solids[J]. 2012, 358(5): 931-940.

[8] Lie Wang, Qiang Xu, et al. Research progress of interfaces and optimization of polymer solid electrolytes. Journal of Chemical Engineering of Chinese Universities[J]. 2023, 37(1)

[9] Chunying Zhang, Yahui Ma, et al. The summarize of current development status of solid state battery technology. Modern Vehicle Power[J]. 2023, 192(4)

[10] Nan Meng, Xiaogang Zhu, et al. Particles in composite polymer electrolyte for solid-state lithium batteries: A review. Particuology[J]. 2022, 60:14-36

[11] D. M. Reinoso, M. A. Frechero. Strategies for rational design of polymer-based solid electrolytes for advanced lithium energy storage applications. Strategies for rational design of polymer-based solid electrolytes for advanced lithium. Energy Storage Materials[J]. 2022, 52:430-464

[12] Ying Zheng, Chaozhi Wang, et al. Crosslinked polymer electrolyte constructed by metal-oxo clusters for solid lithium metal batteries. Energy Storage Materials[J]. 2023, 57:540-548

[13] Kurimamachiya, et al. Lithium Dendrite Formation on a Lithium Metal Anode from Liquid, Polymer and Solid Electrolytes. Electrochemistry[J]. 2016, 84(4):210-218

[14] P.V. Wright. Electrical conductivity in ionic complexes of poly (ethylene oxide). British Polymer Journal[J]. 1975, 7(5): 319-327

[15] K. Sundaramahalingam, D. Vanitha, et al. Electrical properties of lithium bromide poly ethylene oxide / poly vinyl pyrrolidone polymer blend electrolyte. Physica B: Condensed Matter[J]. 2019, 533:120-126

[16] Song Duan, Lanting Qian, et al. Mechanisms of the Accelerated Li+ Conduction inMOF-Based Solid-State Polymer Electrolytes forAll-Solid-State Lithium Metal Batteries. Advanced Materials[J]. 2024, 36(32)

[17] Bhargabi Halder, et al. Review on composite polymer electrolyte using PVDF-HFP for solid-state lithium-ion battery. Materials Today Chemistry[J]. 2024, 36

[18] Yong Cheng, Zhichao Cai, et al. Zwitterionic Cellulose-Based Polymer Electrolyte Enabled by Aqueous Solution Casting for High-Performance Solid-State Batteries. Angewandte Chemie[J]. 2024, 136(30)

[19] Kashif Khan, Muhammad Bilal Hanif, Hu Xin, et al. PEO-Based Solid Composite Polymer Electrolyte for High Capacity Retention All-Solid-State Lithium Metal Battery. Small[J]. 2024, 20(4)

[20] Furui Ma, Yuxiang Liu, Tao Huang, Xuanru Du, et al. Facile in situ polymerization synthesis of poly (ionic liquid)-based polymer electrolyte for high-performance solid-state batteries. Energy Conversion and Management: X[J]. 2024, 22

[21] Min Zhang, Helin Wang, Ahu Shao, et al. Enabling 4.5 V Solid Polymer Batteries through a 10 μm, Crosslinked Polyether Electrolyte. Advanced Energy Materials[J]. 2024, 14(14)

[22] Su Wang, Qifang Sun, Qing Zhang,et al. Li-Ion Transfer Mechanism of Ambient-Temperature Solid Polymer Electrolyte toward Lithium Metal Battery. Advanced Energy Materials[J]. 2024, 13(16)

[23] Fei Pei, Lin Wu, Yi Zhang, Yaqi Liao, et al. Interfacial self-healing polymer electrolytes for long-cycle solid-state lithium-sulfur batteries. Nature Communications[J]. 2024, 15

[24] Weiran Zhang, Volodymyr Koverga, Sufu Liu, et al. Single-phase local-high-concentration solid polymer electrolytes for lithium-metal batteries. Nature Energy[J]. 2024, 9: 386-400

Downloads

Published

07-11-2024

How to Cite

Zhou, H. (2024). Research Progress on Improvement Strategies of Polymer Electrolytes in Solid-State Batteries. Highlights in Science, Engineering and Technology, 116, 302-307. https://doi.org/10.54097/fyphrv62