Highly Efficient Silicon-Based Anodes for Lithium-Ion Batteries
DOI:
https://doi.org/10.54097/y6xnp393Keywords:
Silicon-based anode; lithium-ion battery; electrode; electric vehicle.Abstract
As the world shifts toward a more sustainable society, the advancement of high-performance lithium-ion battery (LIB) technology becomes increasingly vital in addressing rising CO2 levels. The necessity for higher energy density, propelled by the progression of electric vehicles, hybrid electric vehicles, and portable electronics, has highlighted the limitations of traditional graphite anodes. Silicon-based anodes, with their superior theoretical capacity, present a promising alternative. This paper explores the working mechanisms of LIBs and delves into why silicon is an ideal material for anodes. It also delivers an exhaustive overview of Si-based electrodes, emphasizing the significant challenges they face, such as extreme volume expansion and unstable solid electrolyte interface (SEI) formation, which contribute to a shortened battery lifespan. Potential solutions, including nanostructured designs and novel binder formulations, are discussed, highlighting their advantages and current limitations. The benefits and challenges of Si-based materials as LIB anodes are summarized to guide future research and development in this critical area.
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[1] Pasha Junayed, Li Bokang, Elmi Zeinab, et al. Electric vehicle scheduling: State of the art, critical challenges, and future research opportunities. Journal of Industrial Information Integration, 2024, 38: 100561. DOI: https://doi.org/10.1016/j.jii.2024.100561
[2] Yan Jin, Zhu Bin, Lu Zhenda, et al. Challenges and recent progress in the development of Si anodes for lithium‐ion battery. Advanced Energy Materials, 2017, 7(23): 1700175. DOI: https://doi.org/10.1002/aenm.201700715
[3] Maziar Ashuri, He Qianran, Shaw L Leon. Silicon as a potential anode material for Li-ion batteries: where size, geometry and structure matter. Nanoscale, 2016, 8(1): 74-103. DOI: https://doi.org/10.1039/C5NR05116A
[4] Ge Mingzheng, Cao Chunyan, Biesold Gill M, et al. Recent advances in silicon‐based electrodes: from fundamental research toward practical applications. Advanced Materials, 2021, 33(16): 2004577. DOI: https://doi.org/10.1002/adma.202004577
[5] Zuo Xiuxia, Zhu Jin, Mueller-Buschbaum Peter, et al. Silicon based lithium-ion battery anodes: A chronicle perspective review. Nano Energy, 2017, 31: 113-143. DOI: https://doi.org/10.1016/j.nanoen.2016.11.013
[6] Yoshiyuki Kubota, Escaño Mary Clare Sison, Nakanishi Hiroshi, et al. Crystal and electronic structure of Li15Si4. Journal of Applied Physics, 2007, 102 (5): 053704. DOI: https://doi.org/10.1063/1.2775999
[7] Matthew Li, Lu Jun, Chen Zhongwei, et al. 30 years of lithium-ion batteries. Advanced Materials, 2018, 30(33): 1800561. DOI: https://doi.org/10.1002/adma.201800561
[8] He Yang, Jiang Lin, Chen Tianwu, et al. Progressive growth of the solid–electrolyte interphase towards the Si anode interior causes capacity fading. Nature Nanotechnology, 2021, 16(10): 1113-1120. DOI: https://doi.org/10.1038/s41565-021-00947-8
[9] Liu, Tiefeng, Zhang Ben, Sheng Owei, et al. Research progress of the binders for the silicon anode. Chemical Journal of Chinese Universities-Chinese, 2021, 42(5): 1446-1463.
[10] Liu, Xiaohua, Zhong Li, Huang Shan, et al. Size-dependent fracture of silicon nanoparticles during lithiation. ACS Nano, 2012, 6(2): 1522-1531. DOI: https://doi.org/10.1021/nn204476h
[11] Su Xin, Wu Qingliu, Li Juchuan, et al. Silicon-based nanomaterials for lithium-ion batteries: A review. Advanced Energy Materials, 2014, 4(1): 1300882. DOI: https://doi.org/10.1002/aenm.201300882
[12] Li Peng, Hwang Jang-Yeon, Sun Yang-Kook. Nano/microstructured silicon–graphite composite anode for high-energy-density Li-ion battery. ACS Nano, 2019, 13(2): 2624-2633. DOI: https://doi.org/10.1021/acsnano.9b00169
[13] Wu Hui, Chan Gerentt, Choi Jang Wook, et al. Stable cycling of double-walled silicon nanotube battery anodes through solid–electrolyte interphase control. Nature Nanotechnology, 2012, 7(5): 310-315. DOI: https://doi.org/10.1038/nnano.2012.35
[14] Yoon Hyungsub, Behera Promoda, Lim Sooman, et al. Review of the mechanistic and structural assessment of binders in electrodes for lithium-ion batteries. International Journal of Energy Research, 2024, 2024(1): 8893580. DOI: https://doi.org/10.1155/2024/8893580
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